Q. Two balloons are filled, one with pure He gas and the other by air, respectively. If the pressure and temperature of these balloons are same then the number of molecules per unit volume is:

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Solution:

Ideal gas equation can be written as

In this equation,
number of moles of the gas
pressure of the gas
volume of the gas
universal gas constant
and temperature of the gas
From Eq. (i), we have
constant
So, at constant pressure and temperature, all gases will contain equal number of molecules per unit volume.
This result is nothing but Avogadro's law.