Q.
The Van't Hoff factor of solutes A,B and C in aqueous solutions are 0.8,1.6 and 1.2 respectively. The freezing point of equimolar solutions follow the order :
Formula of depression in freezing point is as follow- ΔTf=i×Kf× molality
When solvent and molality of different salt is same then ΔTf∝i
More the Van't Hoff factor of solutes and more will be the depression in freezing point and lesser will be the freezing point.
Given for solute A,B and C the Van't Hoff factor's are 0.8,1.6 and 1.2 respectively.
As for solute B the Van't Hoff factor is maximum so its freezing point will be minimum.
Similarly for solute A the Van't Hoff factor is minimum so its freezing point will be maximum.
Hence the freezing point of equimolar solutions follow the order as A>C>B .