Q. The Van't Hoff factor of solutes and in aqueous solutions are and respectively. The freezing point of equimolar solutions follow the order :

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Solution:

Formula of depression in freezing point is as follow-
molality
When solvent and molality of different salt is same then
More the Van't Hoff factor of solutes and more will be the depression in freezing point and lesser will be the freezing point.
Given for solute and the Van't Hoff factor's are and respectively.
As for solute the Van't Hoff factor is maximum so its freezing point will be minimum.
Similarly for solute the Van't Hoff factor is minimum so its freezing point will be maximum.
Hence the freezing point of equimolar solutions follow the order as .