Q.
The total energy of an electron in the first excited state of the hydrogen atom is about −3.4eV . The potential energy of the electron in this state is
The kinetic energy of an electron, (KE)=2rKZe2
The potential energy of an electron, (PE)=r−KZe2⇒PE=−2KE
In this calculation, the electric potential and potential energy are zero at infinity.
Total energy =PE+KE=−2KE+KE=−KE PE of an electron in this first excited state =−2KE=−2(3.4)=−6.8eV