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Question
Chemistry
The stability of carbanions in the following
Q. The stability of carbanions in the following
5570
195
AIPMT
AIPMT 2008
Organic Chemistry – Some Basic Principles and Techniques
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A
(i) > (ii) > (iii) > (iv)
41%
B
(ii) > (iii) > (iv) > (i)
24%
C
(iv) > (ii)>(iii)>(i)
21%
D
(i) > (iii) > (ii) > (i)
14%
Solution:
The carbanion with more s-character is more stable. Thus, the order of stability is
RC
≡
C
⊖
>
C
6
H
5
⊖
>
R
2
C
=
C
H
⊖
>
R
3
C
−
C
⊖
2