Q. The reversible expansion ob an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following statement(s) is (are) correct?Chemistry Question Image

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Solution:

(a) Since, change of state to is isothermal therefore,
(b) Since, change of state to is an adiabatic expansion it brings about cooling of gas, therefore, .
(c) Work done is the area under the curve of diagram. As obvious from the given diagram, magnitude of area under the isothermal curve is greater than the same under adiabatic curve, hence
(d)
In isothermal process, as
In adiabatic process. as .

NOTE Here only magnitudes of work is being considered otherwise both works have negative sign.