Given that R is resultant of P and Q as shown in the figure below, BC=P,CA=Q and BA=R
Given, BA and BC are perpendicular and equal in magnitude. So, from property of triangle, ∠ACB=45∘
Now, BC has to be extended up to D so, that CD=P
Now, CD and CA have the initial point C, so the angle between CD and CA; =180∘−45∘=135∘=43π
So, angle between P and Q is 34π.