Q.
The relative lowering of vapour pressure of a dilute aqueous solution containing non-volatile solute is 0.0125 . The molality of the solution is about
Relative lowering of vapour pressure = mole fraction of solute (Raoults law) PP−PS=X2 PP−PS=mWwM
where w = wt. of solute M = mol. wt. of solvent m = mol. wt of solute W = wt. of solvent 0.0125=mWwM
Or, mWw=180.0125=0.00070
Hence, molality =mWw×1000 =0.0007×1000=0.70