Reflexive: (a,a)⇒gcd of (a,a)=1
Which is not true for every a ϵZ.
Symmetric:
Take a=2,b=1⇒gcd(2,1)=1
Also 2a=4=b
Now when a=1,b=2⇒gcd(1,2)=1
Also now 2a=2=b
Hence a=2b ⇒R is not Symmetric
Transitive:
Let a=14,b=19,c=21 gcd(a,b)=1 gcd(b,c)=1 gcd(a,c)=7
Hence not transitive ⇒R is neither symmetric nor transitive.