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Question
Chemistry
The reduction potential of hydrogen half-cell will be negative if :
Q. The reduction potential of hydrogen half-cell will be negative if :
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AIEEE
AIEEE 2011
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A
p
(
H
2
)
=
2
a
t
m
and
[
H
+
]
=
2.0
M
B
p
(
H
2
)
=
1
a
t
m
and
[
H
+
]
=
2.0
M
C
p
(
H
2
)
=
1
a
t
m
and
[
H
+
]
=
1.0
M
D
p
(
H
2
)
=
2
a
t
m
and
[
H
+
]
=
1.0
M
Solution:
H
+
+
e
−
⟶
2
1
H
2
Apply Nernst equation
E
=
0
−
1
0.059
lo
g
[
H
+
]
P
H
2
2
1
E
=
−
1
0.059
lo
g
1
2
1/2
Therefore
E
is negative.