Q. The reaction of and alcoholic with -toluidine gives

 8672  179 KEAMKEAM 2008Amines Report Error

Solution:

Aliphatic and aromatic primary amines on warming with and alcoholic form isocyanide or carbylamine which has very unpleasant smell. This reaction is known as carbylamine reaction. Since p-toluidine contains an aromatic primary amine group, it undergoes similar reaction and give 4-methyl phenyl isocyanide.

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