Q.
The ratio of translational to rotational kinetic energies at 100K temperature is 3:2. The internal energy (in J) of one mole gas at that temperature is (R=8.3Jmol−1K−1)
According to law of equipartition of energy, energies equally distributes among its degree of freedom.
Let translational and rotational degree of freedom be f1 and f2, respectively. ∴KRKT=23 and KT+KR=U
Hence, the ratio of translational to rotational degrees of freedom is 3:2. Since translational degrees of freedom is 3 , the rotational degrees of freedom must be 2 . ∴ Internal energy (U)=1×(f1+f2)×21RT U=21×5×8.3×100 ⇒U=2075J