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Question
Chemistry
The rate constant for a first order decomposition reaction is given by: log K =10-(1000/ T ). Then, what will be activation energy in kcal / mol ?
Q. The rate constant for a first order decomposition reaction is given by :
lo
g
K
=
10
−
T
1000
. Then, what will be activation energy in
k
c
a
l
/
m
o
l
?
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A
4.60
38%
B
17.6
8%
C
3.2
46%
D
9.8
8%
Solution:
lo
g
K
=
lo
g
A
−
2.303
RT
E
a
…
(1)
lo
g
k
=
10
−
T
1000
(given)
…
(
2
)
Compairing equ. (1) & ( 2
)
2.303
R
E
a
=
1000
E
a
=
4.60
k
c
a
l
m
o
l
−
1