Q. The primary and secondary valencies of chromium in the complex ion, , are respectively

 2791  229 KEAMKEAM 2008Coordination Compounds Report Error

Solution:

The formula of dichlorodioxalatochromium (III) is

Primary valency of a metal in the complex = oxidation number of that metal

Secondary valency of chromium in complex = coordination number

( Coordination number is the number of ligands attached to the central metal ion and oxalate ion is a bidentate ligand i.e, can coordinate at two positions)