Teflon is tetrafluoroethylene. It cannot form H bonds as H atom is not attached to N,O or F.
Nylon −6,6 is a polyamide. It can form hydrogen bonds as H atom is attached to amide N atom.
Polystyrene is a polymer of styrene. It cannot form H bonds as H atom is not attached to N,O or F.
Natural rubber is cis - 1, 4-polyisoprene. It cannot form H bonds as H atom is not attached to N,O or F.
Thus, the polymer containing strong intermolecular forces (e.g. hydrogen bonding) is Nylon - 6,6 .