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Question
Chemistry
The plot of square root of frequency of X-ray emitted against atomic number led to suggestion of which law/rule ?
Q. The plot of square root of frequency of
X
-ray emitted against atomic number led to suggestion of which law/rule ?
1446
234
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MHT CET 2014
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A
Periodic law
B
Modern periodic law
C
Hund’s rule
D
Newland’s law
Solution:
Moseley, gave modern periodic law. He showed that atomic number is more fundamental property of an element than its atomic mass as follows
"The square root of the frequency of a line (of X-ray spectrum) is related to the atomic number
Z
of the target material as,
v
=
a
(
Z
−
b
)
where,
a
=
proportionality constant
Z
=
atomic number
b
=
another constant
L
it, has the same value for all the lines of X-rays spectrum).