Q.
The pH at the equivalent point for the titration of 0.10MKH2BO3 with 0.1MHl is (Ka of H3BO3=12.8×10−10) Report your answer by rounding it up to nearest whole number.
1466
206
NTA AbhyasNTA Abhyas 2020Equilibrium
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Answer: 5
Solution:
First there will be an acid-base reaction between KH2BO3 and HCl .
conc. will become half after reaction of an equal volume of KH2BO3 and HCl
So 50.1=0.05
Now, [H+]=KaC=12.8×10−10×0.05=8×10−6 pH=−log(8×10−6)≈5.0