When the angle between magnetic field B and velocity vector v is 90∘, so the force will be maximum and always perpendicular to motion, so the path will be circular. When the electron is moving at an angle to the field (other than 0∘,90∘, or 180∘ ), then electron moves with constant velocity vcosθ along the field (as no force acts on a charged particle when it moves parallel to the field) and at the same time it is also moving with velocity vsinθ perpendicular to the field due to which it will describe a circle (in a plane perpendicular to the field) of radius r=qBm(vsinθ)
So, the resultant path will be a helix with its axis parallel to the field B as shown in figure.