The ions having unpaired electron are paramagnetic. The ions having Paired electrons are diamagnetic.
(a) Ni2+=1s2,2s2,2p6,3s2,3p6,4s0,3d8 ∴ It has 2 unpaired electrons and is paramagnetic.
(b) Sc3+=1s2,2s2,2p6,3s2,3p6,4s0,3d0 ∴ It has no unpaired electrons and is diamagnetic
(c) Cu+=1s2,2s2,2p6,3s2,3p6,4s0,3d10 ∴ It has no unpaired electrons and is diamagnetic.
(d) Zn2+=1s2,2s2,2p6,3s2,3p6,4s0,3d10 ∴ It has no unpaired electrons and is diamagnetic.