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Question
Chemistry
The paramagnetic behaviour of B2 is due to the presence of
Q. The paramagnetic behaviour of
B
2
is due to the presence of
1766
200
WBJEE
WBJEE 2012
Chemical Bonding and Molecular Structure
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A
2
unpaired electrons in
π
b
MO
44%
B
2
unpaired electrons in
π
∗
MO
19%
C
2
unpaired electrons in
σ
∗
MO
24%
D
2
unpaired electrons in
σ
b
MO
14%
Solution:
B
2
=
5
+
5
=
10
e
−
=
σ
1
s
2
σ
∗
1
s
2
,
σ
2
s
2
σ
2
s
2
,
π
2
p
x
1
,
π
2
p
y
1
Due to the presence of 2 unpaired electrons, in
π
bonding orbitals,
B
2
shows paramagnetic behaviour.