For bcc lattice,
In ΔEFD b2=a2+a2=2a2 b=2a
Now, in △AFD c2=a2+b2 =a2+2a2=3a2 c=3a
Also, 3a=4r 43a=r
In bec, Z=2 ∴ Volume of cube =a3=(34r)3
Packing effeciency
Volume occupied by two = Total volume of unit cell spheres in a unit cell ×100 =[4/3r]32×34πr3×100=68%