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Question
Chemistry
The oxidation states of Cr in [Cr(H2O)6]Cl3, [Cr(C6H6)2], and K2[Cr(CN)2(O)2(O2)(NH3)] respectively are :
Q. The oxidation states of
C
r
in
[
C
r
(
H
2
O
)
6
]
C
l
3
,
[
C
r
(
C
6
H
6
)
2
]
, and
K
2
[
C
r
(
CN
)
2
(
O
)
2
(
O
2
)
(
N
H
3
)]
respectively are :
3214
193
JEE Main
JEE Main 2018
Coordination Compounds
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A
+3, +4, and +6
19%
B
+3, +2, and +4
23%
C
+3, 0, and +6
44%
D
+3, 0, and +4
15%
Solution:
[
C
r
(
H
2
O
)
6
]
C
l
3
⇒
x
+
0
×
6
−
1
×
3
=
0
∴
x
=
+
3
[
C
r
(
C
6
H
6
)
2
]
⇒
x
+
2
×
0
=
0
x
=
0
K
2
[
C
r
(
CN
)
2
(
O
2
)
(
O
2
)
N
H
3
]
⇒
1
×
2
+
x
−
1
×
2
−
2
×
2
−
2
×
1
=
0
⇒
x
−
6
=
0
x
=
+
6