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Tardigrade
Question
Chemistry
The order of reactivities of the following alkyl halides for a SN2 reaction is
Q. The order of reactivities of the following alkyl halides for a
S
N
2
reaction is
1230
235
CMC Medical
CMC Medical 2010
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A
RF
>
RCl
>
RB
r
>
R
I
B
RF
>
RB
r
>
RCl
>
R
I
C
RCl
>
RB
r
>
RF
>
R
I
D
R
I
>
RB
r
>
RCl
>
RF
Solution:
The reactivity order of alkyl halide is
R
−
I
>
R
−
B
r
>
R
−
Cl
>
R
−
F
This order is due to the bond dissociation enthalpy i.e. the energy required to cleave the
C
−
X
bond. Lesser the bond dissociation energy, more will be the reactivity of the haloalkanes.