Amylopectin is branched chain polymer of α -D-glucose units, involving about 1000 or more units per molecule. It is insoluble in water. In amylopectin, chain is formed by C1 and C2 glycosidic linkage whereas branching occurs by C1 and C6 glycosidic linkage. (Structure of glycogen is similar to amylopectin and it is also highly branched).