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Question
Chemistry
The mass of a non-volatile solute of molar mass 60 g mol -1 that should be dissolved in 126 g of water to reduce its vapour pressure nto 99 % wil be
Q. The mass of a non-volatile solute of molar mass
60
g
m
o
l
−
1
that should be dissolved in
126
g
of water to reduce its vapour pressure nto
99%
wil be
2004
220
COMEDK
COMEDK 2012
Solutions
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A
4 g
48%
B
8 g
21%
C
5.6 g
24%
D
3 g
7%
Solution:
Relative lowering in vapour pressure
= mole fraction of the non-volatile solute
p
∘
p
∘
−
p
s
=
x
2
=
w
1
/
M
1
+
w
2
/
M
2
w
2
/
M
2
100
100
−
99
=
126/18
+
w
2
/60
w
2
/60
w
2
=
4.2
=
4
g