The main constituents of acid rain are H2SO4 and HNO3.SO2 and NO2 after oxidation and reaction with H2O are major contributors of acid rain, because polluted air usually contains particulate matter that catalyse their oxidation. 2SO2(g)+O2(g)+2H2O(l)→Sulphuric acid2H2SO4(aq) 4NO2(g)+O2(g)+2H2O(l)→Nitric acid4HNO3(aq)