The isoelectronic species are those species which have same number of electrons.
(a) Sc2+ and V3+
Number of electrons in Sc2+=19
Number of electrons in V3+=21
(b) Mn2+ and Fe3+
Number of electrons in Mn2+=23
Number of electrons in Fe3+=23
(c) Mn3+ and Fe2+
Number of electrons in Mn3+=22
Number of electrons in Fe2+=24
(d) Ni3− and Fe2−
Number of electrons in Ni3−=31
Number of electrons in Fe2−=28
Thus, Mn2+ and Fe3+ are isoelectronic pair