The potential energy of hydrogen atom En=−n213.6eV
So, the potential energy in second orbit is E2=−2213.6eV ⇒E2=−413.6eV =−3.4eV
Now, the energy required to remove an electron from second orbit to infinity is U=E∞−E2 [from work-energy theorem and E∞=0] ⇒U=0−(−3.4)eV
or U=3.4eV
Hence, the required energy is 3.4eV.