Q.
The ionisation potential of hydrogen atom is −13.6eV. An electron in the ground state of a hydrogen atoms absorbs a photon of energy 12.75eV. How many different spectral line can one expect when the electron make a downward transition?
E=E1/n2
Energy used for excitation is 12.75eV ie,(−13.6+12.75)eV=−0.85eV
Energy levels of H-atom
The photons of energy 12.75eV can excite the
fourth level of H-atom. Therefore, six lines will be emitted, (n2(n−1) lines )