Q.
The increasing order of the first ionisation enthalpies of the elements B, P, S and F (lowest first) is
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Classification of Elements and Periodicity in Properties
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Solution:
In general as we move from left to right in a period, the ionisation enthalpy increases with increasing atomic number. The ionisation enthalpy decreases as we move down a group. P(1s22s22p63s23p3) has a stable half filled electronic configuration hence, its ionisation enthalpy is higher than that of S. ∴ Increasing order of ionization energy is B<S<P<F.