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Tardigrade
Question
Chemistry
The heat of neutralization of HCl by NaOH is -55.9 kJ mol-1 and that of HCN is -12.1 kJ; the energy of dissociation of HCN is
Q. The heat of neutralization of HCl by NaOH is
−
55.9
k
J
m
o
l
−
1
and that of HCN is -12.1 kJ; the energy of dissociation of HCN is
1605
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A
43.8 kJ
B
-43.8 kJ
C
-68 kJ
D
68 kJ
Solution:
H
+
+
O
H
−
H
2
O
;
Δ
H
=
−
55.9
k
J
?(i)
H
CN
+
O
H
−
→
H
2
O
+
C
N
−
;
Δ
H
=
−
12.1
k
J
?(ii) On revers Eq. (i) and then adding to Eq. (ii), we get
H
CN
H
+
+
C
N
−
;
Δ
H
=
+
43.8
k
J