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Question
Chemistry
The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of 99 % of the chemical reaction will be (log 2 = 0.301) :
Q. The half life period of a first order chemical reaction is
6.93
minutes. The time required for the completion of
99%
of the chemical reaction will be (
l
o
g
2
=
0.301
) :
1658
181
AIEEE
AIEEE 2009
Chemical Kinetics
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A
230.3
minutes
5%
B
23.03
minutes
13%
C
46.06
minutes
80%
D
460.6
minutes
3%
Solution:
∵
λ
=
t
1/2
0.6932
=
6.93
0.6932
mi
n
−
1
Also
t
=
λ
2.303
l
o
g
[
A
]
[
A
o
]
[
A
o
]
=
initial concentration (amount)
[
A
]
=
final concentration (amount)
∴
t
=
0.6932
2.303
×
6.93
l
o
g
1
100
46.06
minutes