Q. The frequency for a series limit of Balmer and Paschen series respectively are f1 and f3. If the frequency of the first line of Balmer series is f2 then the relation between f1, f2 and f3 is

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Solution:

c=fλ,1λ=fc
1λ=R1P2-1n2
f=Rc1P2-1n2
f2=Rc122-132=Rc14-19=5Rc36
f1=Rc122=Rc4
f3=Rc132=Rc9
   f1-f3=Rc14-19
  f1-f3=f2
   f1-f2=f3