Q.
The equilibrium constant for the reversible reaction, N2+3H2⇌2NH3 is K and for the reaction 21N2+23H2⇌NH3, the equilibrium constant is K′ . K and K′ will be related as
N2(g)+3H2(g)⇌2NH3(g)
From law of mass action, K=[N2][H2]3[NH3]2… (i)
Similarly, for reaction 21N2+23H2⇌NH3 K′=[N2]1/2[H2]3/2[NH3]...(ii)
So, from Eqs.(i) and (ii) K′=K