PhosphoEnolPyruvate (PEP) carboxylase is present in the mesophyll cells of the C4 plants and catalyse the conversion PEP to OxaloAecetate. (OAA), the first 4C stable compound formed in C4 plants formed by the acceptance of atmospheric CO2 by PEP in presence of PEP carboxylase. So, the correct answer is 'PEP Carboxylase'