Q.
The enthalpy of formation of CO(g),CO2(g),N2O(g) and N2O4(g) is -110, -393, +811 and 10 kj/mol respectively. For the reaction, N2O4(g)+3CO(g)→N2O(g)+3CO2(g).ΔHr(kJ/mol) is
N2O4(g)+3CO(g)⟶N2O(g)+3CO2(g) ΔHreaction =∑Heat of formation of products −∑Heat of formation of reactants ΔHreaction =[ΔHfN2O+3×ΔHfCO2]−[ΔHfN2O4+3×ΔHfCO] ΔHr=[+811+3(−393)]−[10+3(−110)] =[811−1179]−[−320]=−368+320 =−48kJ/mol