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Question
Chemistry
The enthalpy of hydrogenation of cyclohexene is -119.5 kJ mol -1 . If resonance energy of benzene is -150.4 kJ mol -1, its enthalpy of hydrogenation would be:-
Q. The enthalpy of hydrogenation of cyclohexene is
−
119.5
k
J
m
o
l
−
1
.
If resonance energy of benzene is
−
150.4
k
J
m
o
l
−
1
, its enthalpy of hydrogenation would be:-
1661
168
AIPMT
AIPMT 2006
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A
−
508.9
K
J
m
o
l
−
1
50%
B
−
2.8.1
K
j
m
o
l
−
1
17%
C
−
269.9
K
J
m
o
l
−
1
33%
D
−
358.5
K
j
m
o
l
−
1
0%
Solution:
∵
Heat of hydrogenation of cyclohaxene
=
−
119.5
k
J
/
m
o
l
∴
Heat of hydrogenation of benzene
=
3
×
−
119.5
=
−
358.5
K
J
/
m
o
l
Resonance energy
=
Observed
Δ
H
−
Calculated
Δ
H
−
150.4
=
−
358.5
−
x
x
=
−
208.1
K
J