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Chemistry
The enthalpy of combustion for the H2, cyclohexene and cyclohexane are -241, -3800 and -3920 kJ mol-1 , respectively. Heat of hydrogenation of cyclohexene is
Q. The enthalpy of combustion for the
H
2
, cyclohexene and cyclohexane are
−
241
,
−
3800
and
−
3920
k
J
m
o
l
−
1
, respectively. Heat of hydrogenation of cyclohexene is
3944
228
UPSEE
UPSEE 2015
Thermodynamics
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A
121
k
J
m
o
l
−
1
B
−
121
k
J
m
o
l
−
1
C
+
242
k
J
m
o
l
−
1
D
−
242
k
J
m
o
l
−
1
Solution:
H
2
+
2
1
O
2
⟶
H
2
O
,
Δ
H
=
−
241
k
J
…
(
i
)
C
6
H
10
+
2
17
O
2
⟶
6
C
O
2
+
5
H
2
O
Δ
H
=
−
3800
k
J
…
(
ii
)
C
6
H
12
+
9
O
2
⟶
6
C
O
2
+
6
H
2
O
Δ
H
=
−
3920
k
J
…
(
iii
)
For the reaction,
C
6
H
10
+
H
2
⟶
C
6
H
12
Adding Eqs. (i) and (ii) then subtracting Eq. (iii), we get
Δ
H
=
−
241
−
3800
−
(
−
3920
)
=
−
121
k
J