Q.
The enthalpies of combustion of carbon and carbon monoxide are −393.5 and −283kJmol−1 respectively. The enthalpy of formation of carbon monoxide per mole is
C(s)+O2(g)⟶CO2(g) ΔH=−393.5kJmol−1 CO(g)+21O2(g)→CO2(g) ΔH=−283kJmol−1
On subtracting equation (ii) from equation (i), we get C(s)+O2(g)→CO(g);ΔH=−110.5kJmol−1
The enthalpy of formation of carbon monoxide
per mole =−110.5kJmol−1