Q.
The density and equivalent weight of a metal are 10.5gcm−3 and 100, respectively. The time required for a current of 3 amp to deposit a 0.005mm thick layer of the same metal on an area of 80cm2 is closest to
Given,
density of metal = 10.5gcm−3
Equivalent weight of metal = 100
Current, I=3A
Area of cross section = 80cm2, length =0.005mm=5×10−4cm
According to Faraday’s second law, W=n×96500eq.wt.×I×t W=1×96500100×3×t....(i)
Also, W = density x volume
= density x area x length =10.5×80×5×10−4=42×10−2...(ii)
Substituting the value of W in Eq. (i), 1×96500100×3×t=42×10−2 t=100×342×10−2×96500=135s