CuSO4 is a salt of weak base [CO(OH)2] and strong acid (H2SO4), hence it will be acidic in nature. Therefore, pH of its solution must be less than 7. NaCl is a salt of strong base (NaOH) and strong acid (HCl), hence it will be neutral in nature. Therefore pH of its solution will be 7. Similarly, H2O is neutral itself in nature, therefore its pH also will be 7. On the other hand, NaCN is a salt of strong base (NaOH) and weak acid (HCN), so its solution must be basic in nature showing pH greater than 7. Hence, correct order of pH is as follows : CuSO4<NaCl=H2O<NaCN.