AlkyI halides are more reactive than aryl halides. Among alkyl halides, 3∘ alkyl halides (III) are more reactive than 2∘ alkyl halides. (IV) Among aryl halides, aryl halides having electron with dwawing −NO2 groups at o− and p− positions (i.e. II) are more reactive than simple aryl halides (I) thus, the overall reactivity increases in the order. I<II<IV<III