Q.
The correct order of EM2+/M0 values with negative sign for the four successive elements Cr,Mn,Fe and Co is
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AIEEEAIEEE 2010The d-and f-Block Elements
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Solution:
Usually across the first transition series, the negative values for standard electrode potential decrease except for Mn due to stable d5 configuration.
The electronic configuration of various elements in Mn2+ state is: Cr−[Ar]3d4 Mn−Cr−[Ar]3d5 -half filled- most stable. Fe−Cr−[Ar]3d6 Co−Cr−[Ar]3d7
So, based on above facts the correct order is: Mn>Cr>Fe>Co.