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Question
Chemistry
The correct order in aqueous medium of basic strength in case of methyl substituted amines is :
Q. The correct order in aqueous medium of basic strength in case of methyl substituted amines is :
361
123
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Amines
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A
N
H
3
>
M
e
3
N
>
M
e
N
H
2
>
M
e
2
N
H
14%
B
M
e
2
N
H
>
M
e
3
N
>
M
e
N
H
2
>
N
H
3
14%
C
M
e
2
N
H
>
M
e
N
H
2
>
M
e
3
N
>
N
H
3
71%
D
M
e
3
N
>
M
e
2
N
H
>
M
e
N
H
2
>
N
H
3
0%
Solution:
In aqueous medium basic strength is dependent on electron density on nitrogen as well as solvation of cation formed after accepting
H
+
. After considering all these factors overall basic strength order is
M
e
2
N
H
>
M
e
N
H
2
>
M
e
3
N
>
N
H
3