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Question
Chemistry
<img class=img-fluid question-image alt=image src=https://cdn.tardigrade.in/img/question/chemistry/1261e5031adc13da6b746792d39476bc-.png /> The correct decreasing order of pKb is
Q.
The correct decreasing order of
p
K
b
is
3172
213
AIIMS
AIIMS 2011
Amines
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A
I > II > III > IV
13%
B
III > IV > II > I
15%
C
II > III > IV > I
15%
D
IV > II > I > III
57%
Solution:
Substituent with strong
+
R effect,
+
I
effect and weaker
−
I
effect increases the basicity. Hence
P
K
b
decreases. Also, alkylamines are stronger bases than arylamines. So, the order is (d).