(A) 2B+2NH3→2BN+3H2
Boron produced BN with ammonia but Boron is element not compound. So that this option not involve in answer.
(B) 3B2H6+6NH3→3[BH2(NH3)2]+[BH4−]T=200∘C2B3N3H6+12H2B3N3H6T>200∘C(BN)x
(C) B2O3(ℓ)+2NH31200∘C2BN(s)+3H2O(g)
(D) HBF4+NH3→NH4[BF4]