When an atom comes down from some higher energy level to the second energy (n=2),
then the lines of spectrum are obtained in visible part and give the Balmer series. λ1=R(221−n21), n=3,4,5... For second line n=4 ∴λ1=R(221−421) =163R⇒λ=3R16 R=1.097×107m−1 λ=3×1.097×10716 =4860×10−10m ⇒λ=4860A˚ which corresponds to colour blue.