Q. The colligative properties of electrolytes require a slightly diferent approach than the one used for the colligative properties of non- electrolytes. The electrolytes dissociate
into ions in solution. It is the number of solute particles that determine the colligative properties of a solution. The electrolyte solutions, therefore show abnormal colligative properties. To account for this effect we define a quantity; called the van't Hoff factor which is given by [solution]

(for non - electrolytes);
(for electrolytes, undergoing dissociation)
(for solute, undergoing association)
For a solution of a non electrolyte in water, the van't Hoff factor is

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Solution:

Correct answer is (d)