Q.
The change in the entropy of a 1 mole of an ideal gas which went through an isothermal process from an initial state (P1,V1,T) to the final state (P2,V2,T) is equal to:
Key Idea : In an isothermal process, there is no change in internal energy of gas,
ie., ΔU=0.
The change in entropy of an ideal gas ΔS=TΔQ…(i)
In isothermal process, there is no change in internal energy of gas,
i.e., ΔU=0 ∴ΔU=ΔQ−W ⇒0=ΔQ−W ⇒ΔQ=W
i.e., ΔQ= work done by gas in isothermal process which went through from (P1,V1,T) to (P2,V2,T)
or ΔQ=μRTloge(V1V2)…(ii).
For 1 mole of an ideal gas, μ=1
So, from Eqs. (i) and (ii), we get
or ΔS=Rloge(V1V2) =Rln(V1V2)