Compounds NH3PH3AsH3SbH3Boiling point (in K) 238185211254
(i) From PH3 to SbH3 boiling point increases regularly due to increase in van der Waals forces of attraction.
(ii) NH3 has exceptionally high boiling point due to hydrogen bonding. ∴ The boiling points are of the order SbH3>NH3>AsH3>PH3