Q.
The atomic masses of He and Ne are 4 and 20 amu, respectively. The value of the de-Broglie wavelength of He gas at −73∘C is ' M ' times that of the de-Broglie wavelength of Ne at 727∘C.M is
Atomic mass of helium and neon is 4amu and 20amu mHe=4amu and mNe=20amu THe=−73∘C=(273+(−73))K=200K TNe=727∘C=(273+727)K=1000K
As we know that the de Broglie wavelength of gas molecules is given byλ=3mkTh
where, k= Boltzmann constant
λHe=MλNe (Given) ⇒3×4×k×200h= M 3×20×k×1000h ⇒M=25=5
Hence, the value of de Broglie wavelength of helium is 5 times the de Broglie wavelength of neon.